SHERWIN-WILLIAMS CO -- UPSIDE DOWN MARKING PAINTS-3, 7147  -- 8010-00N054749
<pre>=====================  Product Identification  =====================

Product ID:UPSIDE DOWN MARKING PAINTS-3, 7147
MSDS Date:02/20/1993
FSC:8010
NIIN:00N054749
=== Responsible Party ===
Company Name:SHERWIN-WILLIAMS CO
Address:6830 COCHRAN RD
City:SOLON
State:OH
ZIP:44199
Country:US
Info Phone Num:800-247-3266
Emergency Phone Num:216-292-7400
CAGE:DO642
=== Contractor Identification ===
Company Name:KRYLON PRODUCTS
Address:31500 SOLON ROAD
Box:City:SOLON
State:OH
ZIP:44139
Country:US
Phone:800-832-2541/216-566-2917
CAGE:87187
Company Name:SHERWIN-WILLIAMS CO THE SPECIALTY DIV.
Address:6830 COCHRAN RD.
Box:6709
City:SOLON
State:OH
ZIP:44139-3908
Phone:216-292-7400
CAGE:DO642

=============  Composition/Information on Ingredients  =============

Ingred Name:PROPANE (PROPELLANT). VP:780.
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 16%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT

Ingred Name:VM & P NAPHTHA; (ALIPHATIC PETROLEUM DISTILLATE). VP:2.
CAS:64742-89-8
Fraction by Wt: 12%
OSHA PEL:100 PPM (MFR)
ACGIH TLV:100 PPM (MFR)

Ingred Name:NAPHTHOL SPIRITS; (V. M. & P. NAPHTHA). VP:12.
CAS:64742-48-9
Fraction by Wt: 4%
OSHA PEL:300 PPM (MFR)
ACGIH TLV:300 PPM (MFR)

Ingred Name:TOLUENE  (SARA III). VP:22.
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 13%
OSHA PEL:200 PPM
ACGIH TLV:50 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:CARBONIC ACID, CALCIUM SALT (1:1); CALCIUM CARBONATE
CAS:471-34-1
RTECS #:FF9335000
Fraction by Wt: 10%
OSHA PEL:10 MG/M3 (MFR)
ACGIH TLV:10 MG/M3 (MFR)

Ingred Name:VOLATILE ORGANIC COMPONENT (BAAQMD RULE 40): 46% (WT).
RTECS #:9999999VO
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SUPDAT:TOLUENE APPEARS ON NAVY LIST OF OCCUP CHEM REPRO
    HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7:CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS
    INFO .
RTECS #:9999999ZZ

Ingred Name:OTHER PREC:GROUNDING PROCS. CONTENTS UNDER PRESS. DO NOT
    PUNCTURE, INCIN/EXPOS TO TEMP >120F. HEAT FROM (ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9:SUNLIGHT, RADIATORS, STOVES, HOT WATER & OTHER HEAT
    SOURCES COULD CAUSE CNTNR TO BURST. DO NOT TAKE (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10:INTERNALLY. KEEP OUT OF REACH OF CHILDREN. USE ONLY
    W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID CONT(ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11:W/SKIN & EYES. THIS COATING MAY CONTAIN MATLS
    CLASSIFIED AS NUISANCE PARTICULATES WHICH MAY BE PRESENT AT(ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12:HAZ LEVELS ONLY DURING SANDING/ABRADING OF DRIED
    FILM. IF NO SPECIFIC DUSTS ARE LISTED, APPLIC LIMS FOR (ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13:NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 TDUST, OSHA
    PEL 15 MG/M3 TDUST;5 MG/M3 RESP.
RTECS #:9999999ZZ

Ingred Name:RESP PROT:DUST WHICH MAY BE GENERATED FROM THIS PRODUCT,
    UNDERLYING PAINT OR THE ABRASIVE.
RTECS #:9999999ZZ

Ingred Name:VENT:1910.107, 1910.108.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:NO  Ingestion:NO
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE
    CONT, DEPENDING ON CNDTNS OF USE. TO MIN EXPOS, FOLLOW RECS FOR
    PROPER USE, VENT & PERSONAL PROT EQUIP. ACUTE:IRRIT OF EYES, SKIN &
    RESP SYS. MAY CAUSE NERV SYS DEP RESS. EXTREME OVEREXP MAY RSLT IN
    UNCON& POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:OF EXCESSIVE EXPOS TO VAPS/SPRAY
    MISTS. REDNESS & ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESSIVE
    SKIN EXPOS. CHRONIC:PRLNG OVEREXP TO SOLV INGS MAY CAUSE ADVERSE
    EFTS TO LIVER, URINARY, BL OOD-FORMING, CVS & REPRO SYS. RPTS
    HAVEASSOC RPTD & PRLNG OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS
    DMG. (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

=======================  First Aid Measures  =======================

First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM &
    QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE
    CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE
    AMOUNTS OF	WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION.
    INGEST:GET MEDICAL ATTENTION.

=====================  Fire Fighting Measures  =====================

Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:0.7%
Upper Limits:36.5%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
    WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF.
    WATER MAY BE USED TO COOL CLSD CNTNRS(SUPDAT)
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT, ELEC EQUIP, SPKS &
    OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT.
    APPLICATION TO HOT SURFS REQS SPECIAL PRECS. (SUPP DATA)

==================  Accidental Release Measures  ==================

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE &
    REMOVE W/INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:DOL STOR CATEGORY - 1A. CONTENTS ARE
    EXTREMELY FLAMM. KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. VAPS WILL
    ACCUM READILY & MAY IGNITE EXPLOSIVELY.
Other Precautions:DURING USE & UNTIL ALL VAPS ARE GONE: KEEP AREA
    VENTILATED; DO NOT SMOKE; EXTING ALL FLAMES, PILOT LIGHTS &
    HEATERS; TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER
    SOURCES OF IGNIT. CONSULT NFPA  CODE. USE APPRVD BONDING & (ING 9)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
    APPLIC LIMS BY VENT, WEAR PROPERLY FITTED NIOSH/MSHA APPRVD ORG
    VAP/PARTICULATE RESP FOR PROT AGAINST INGS. WHEN SANDING/ABRADING
    DRIED FILM, WEAR NIOSH/MS HA APPRVD DUST/MIST RESP FOR (ING 15)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPT IF EXPOS TO INGS IS
    MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS (ING 16)
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC:TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN
    EXPOS TO EXTREME HEAT. EXPLO HAZ:DURING EMER CNDTNS OVEREXP TO
    DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT.
    OBTA IN MED ATTN. EFTS OF OVEREXP:INTENTIONAL MISUSE BY DELIB CONC
    & INHALING CONTENTS MAY BE HARMFUL/FATAL. NOTE: (ING 7)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:<0F,<-18C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate &amp; Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
    MONOXIDE, OXIDES OF METALS IN INGS.

====================  Disposal Considerations  ====================

Waste Disposal Methods:WASTE FROM THESE PRODS MAY BE HAZ AS DEFINED
    UNDER RCRA 40 CFR 1910.261. WASTE MUST BE TESTED FOR IGNITABILITY
    TO DETERMINE APPLIC EPA WASTE NUMBERS. DO NOT INCIN. DEPRESSURIZE
    CNTNR. DISP OF I/A/W FE D, STATE & LOCAL REGS REGARDING POLLUTION.

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