SHERWIN-WILLIAMS CO -- UPSIDE DOWN MARKING PAINTS-3, 7141  -- 8010-00N054743
<pre>=====================  Product Identification  =====================

Product ID:UPSIDE DOWN MARKING PAINTS-3, 7141
MSDS Date:02/20/1993
FSC:8010
NIIN:00N054743
=== Responsible Party ===
Company Name:SHERWIN-WILLIAMS CO
Address:6830 COCHRAN RD
City:SOLON
State:OH
ZIP:44199
Country:US
Info Phone Num:800-247-3266
Emergency Phone Num:216-292-7400
CAGE:DO642
=== Contractor Identification ===
Company Name:KRYLON PRODUCTS
Address:31500 SOLON ROAD
Box:City:SOLON
State:OH
ZIP:44139
Country:US
Phone:800-832-2541/216-566-2917
CAGE:87187
Company Name:SHERWIN-WILLIAMS CO THE SPECIALTY DIV.
Address:6830 COCHRAN RD.
Box:6709
City:SOLON
State:OH
ZIP:44139-3908
Phone:216-292-7400
CAGE:DO642

=============  Composition/Information on Ingredients  =============

Ingred Name:PROPANE (PROPELLANT). VP:780.
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 10%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT

Ingred Name:PROPANE, 2-METHYL-; (2-METHYLPROPANE (PROPELLANT)). VP:780.
CAS:75-28-5
RTECS #:TZ4300000
Fraction by Wt: 10%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:XYLENE  (SARA III). VP:5.
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 10%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM;150 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:NAPHTHOL SPIRITS; (V. M. & P. NAPHTHA). VP:12.
CAS:64742-48-9
Fraction by Wt: 2%
OSHA PEL:300 PPM (MFR)
ACGIH TLV:300 PPM (MFR)

Ingred Name:METHANOL; (METHYL ALCOHOL)	(SARA III). VP:82.
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 2%
OSHA PEL:200 PPM, S
ACGIH TLV:200 PPM;250 STEL, S
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:ACETONE  (SARA III). VP:100.
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 10%
OSHA PEL:1000 PPM
ACGIH TLV:750 PPM;1000 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:CARBONIC ACID, CALCIUM SALT (1:1); CALCIUM CARBONATE
CAS:471-34-1
RTECS #:FF9335000
Fraction by Wt: 9%
OSHA PEL:10 MG/M3 (MFR)
ACGIH TLV:10 MG/M3 (MFR)

Ingred Name:BARIUM SULFATE
CAS:7727-43-7
RTECS #:CR0600000
Fraction by Wt: 11%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST

Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 3%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST

Ingred Name:VOLATILE ORGANIC COMPONENT (BAAQMD RULE 40): 50% (WT).
RTECS #:9999999VO
ACGIH TLV:N/K 

Ingred Name:SUPDAT:OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG.
    INTENTIONAL MISUSE BY DELIB CONCENTRATING & INHALING (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11:CONTENTS CAN BE HARMFUL OR FATAL.
RTECS #:9999999ZZ

Ingred Name:OTHER PREC:GROUNDING PROCS. CONTENTS UNDER PRESS. DO NOT
    PUNCTURE, INCIN/EXPOS TO TEMP >120F. HEAT FROM (ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13:SUNLIGHT, RADIATORS, STOVES, HOT WATER & OTHER HEAT
    SOURCES COULD CAUSE CNTNR TO BURST. DO NOT TAKE (ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14:INTERNALLY. KEEP OUT OF REACH OF CHILDREN. USE ONLY
    W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID CONT(ING 16)
RTECS #:9999999ZZ

Ingred Name:ING 15:W/SKIN & EYES. THIS COATING MAY CONTAIN MATLS
    CLASSIFIED AS NUISANCE PARTICULATES WHICH MAY BE PRESENT AT(ING 17)
RTECS #:9999999ZZ

Ingred Name:ING 16:HAZ LEVELS ONLY DURING SANDING/ABRADING OF DRIED
    FILM. IF NO SPECIFIC DUSTS ARE LISTED, APPLIC LIMS FOR (ING 18)
RTECS #:9999999ZZ

Ingred Name:ING 17:NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 TDUST, OSHA
    PEL 15 MG/M3 TDUST;5 MG/M3 RESP.
RTECS #:9999999ZZ

Ingred Name:RESP PROT:DUST WHICH MAY BE GENERATED FROM THIS PRODUCT,
    UNDERLYING PAINT OR THE ABRASIVE.
RTECS #:9999999ZZ

Ingred Name:VENT:1910.107, 1910.108.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:NO  Ingestion:NO
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE
    CONT, DEPENDING ON CNDTNS OF USE. TO MIN EXPOS, FOLLOW RECS FOR
    PROPER USE, VENT & PERSONAL PROT EQUIP. ACUTE:IRRIT OF EYES, SKIN &
    RESP SYS. MAY CAUSE NERV SYS DEP RESS. EXTREME OVEREXP MAY RSLT IN
    UNCON& POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:OF EXCESSIVE EXPOS TO VAPS/SPRAY
    MISTS. REDNESS & ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESSIVE
    SKIN EXPOS. CHRONIC:PRLNG OVEREXP TO SOLV INGS MAY CAUSE ADVERSE
    EFTS TO LIVER, URINARY, BL OOD-FORMING, CVS & REPRO SYS. RATS EXPOS
    TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG CANCER,
    HOWEVER, (SUPDAT)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

=======================  First Aid Measures  =======================

First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM &
    QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE
    CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE
    AMOUNTS OF	WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION.
    INGEST:GET MEDICAL ATTENTION.

=====================  Fire Fighting Measures  =====================

Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:0.7%
Upper Limits:36.5%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
    WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF.
    WATER MAY BE USED TO COOL CLSD CNTNRS(SUPDAT)
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT, ELEC EQUIP, SPKS &
    OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT.
    APPLICATION TO HOT SURFS REQS SPECIAL PRECS. (SUPP DATA)

==================  Accidental Release Measures  ==================

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE &
    REMOVE W/INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:DOL STOR CATEGORY - 1A. CONTENTS ARE
    EXTREMELY FLAMM. KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. VAPS WILL
    ACCUM READILY & MAY IGNITE EXPLOSIVELY.
Other Precautions:DURING USE & UNTIL ALL VAPS ARE GONE: KEEP AREA
    VENTILATED; DO NOT SMOKE; EXTING ALL FLAMES, PILOT LIGHTS &
    HEATERS; TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER
    SOURCES OF IGNIT. CONSULT NFPA  CODE. USE APPRVD BONDING & (ING 13)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
    APPLIC LIMS BY VENT, WEAR PROPERLY FITTED NIOSH/MSHA APPRVD ORG
    VAP/PARTICULATE RESP FOR PROT AGAINST INGS. WHEN SANDING/ABRADING
    DRIED FILM, WEAR NIOSH/MS HA APPRVD DUST/MIST RESP FOR (ING 19)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPT IF EXPOS TO INGS IS
    MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS (ING 20)
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC:TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN
    EXPOS TO EXTREME HEAT. EXPLO HAZ:DURING EMER CNDTNS OVEREXP TO
    DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT.
    OBTA IN MED ATTN. EFTS OF OVEREXP:SUCH EXPOSLEVELS ARE NOT
    ATTAINABLE IN WORKPLACE. RPTS HAVE ASSOC RPTD & PRLNG (ING 11)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:<0F,<-18C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate &amp; Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
    MONOXIDE, OXIDES OF METALS IN INGS.

====================  Disposal Considerations  ====================

Waste Disposal Methods:WASTE FROM THESE PRODS MAY BE HAZ AS DEFINED
    UNDER RCRA 40 CFR 1910.261. WASTE MUST BE TESTED FOR IGNITABILITY
    TO DETERMINE APPLIC EPA WASTE NUMBERS. DO NOT INCIN. DEPRESSURIZE
    CNTNR. DISP OF I/A/W FE D, STATE & LOCAL REGS REGARDING POLLUTION.

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